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Chimie supramoléculaire et catalyse

Projet de recherche P5/03 (Action de recherche P5)
Description - Documentation

Personnes :

Description :

La chimie est qualifiée de supramoléculaire lorsqu'elle contribue à la mise en place d'assemblages de molécules par l'intermédiaire de liaisons non-covalentes. Ce sont les caractéristiques structurales des molécules, voire des particules, impliquées qui contrôlent la spécificité des auto-assemblages formés à l'échelle soit du nanomètre (chimie nanoscopique), soit du micromètre (chimie mésoscopique).

Le but de ce projet est de développer de nouvelles méthodologies conduisant à de nouveaux systèmes, de comprendre la logique qui pousse à la formation de structures bi- et tri-dimensionnelles, de développer des méthodes et outils qui permettent d'analyser, de stimuler et de manipuler des structures supramoléculaires afin d'en exploiter les propriétés spécifiques. Ce réseau ambitionne de poursuivre l'étude des différents aspects de la chimie supramoléculaire en relation étroite avec la chimie organique et la chimie-physique, la catalyse, la chimie des polymères et la chimie biomimétique. Les maîtres mots du projet sont : systèmes supramoléculaires résolus au niveau moléculaire, auto-organisation, dimensionnalité, chiralité, réactivité et hypersélectivité. Comparé au projet précédent (phase IV), l'accent est mis sur de nouveaux aspects émergents, comme les aspects biomimétiques, et sur les domaines les plus prometteurs dégagés antérieurement. Au cours de la phase IV, une collaboration fructueuse s'est développée entre partenaires possédant une expertise, tant expérimentale que théorique, complémentaire. En conséquence, les travaux de recherche, propres aux quatre disciplines précitées, seront traités par des partenaires rompus à mettre en commun leur expertise scientifique et leurs ressources techniques et instrumentales.

La démarche, appliquée dans le domaine de la chimie organique et de la chimie physique, repose sur l'approche "bottom-up" des structures organiques et hybrides organiques/inorganiques de fonctionnalité accrue, selon des méthodologies théoriques et expérimentales améliorées. En particulier, des structures dendritiques, des matériaux photoniques, incluant des systèmes "band gap" et des oligomères conjugués, seront développés. L'interaction de ces matériaux avec des polymères et des biomatériaux sera également prise en compte.

Pour ce qui concerne la catalyse supramoléculaire, l'effort de recherche sera poursuivi en catalyse supramoléculaire hypersélective, avec une attention toute particulière portée aux aspects spécifiques de la biocatalyse. La démarche intégrée, présidant au développement de solides supramoléculaires, à leurs propriétés d'adsorption et à la modélisation de leur comportement cinétique, sera généralisée et étendue à des matériaux catalytiques de porosité accrue en combinaison avec des réactifs de plus grande taille. Les sites actifs seront également modélisés. Le fil conducteur des activités est la transposition des concepts de chimie supramoléculaire et de biochimie à la catalyse hétérogène et à la biocatalyse, afin de développer de nouveaux catalyseurs supramoléculaires, hétérogènes et sélectifs et de comprendre, à l'échelle moléculaire, les raisons de leur sélectivité. Le réseau possède toute l'expertise requise pour atteindre les objectifs fixés, y compris la modification d'enzymes dans une direction prédéterminée.

Le premier objectif des travaux relatifs à la chimie des polymères est l'amélioration constante du contrôle de la synthèse de structures toujours mieux définies bien que toujours plus complexes et plus difficiles à réaliser. Le second objectif général vise à développer et à exploiter la connaissance des phénomènes d'auto-association des (co)polymères afin de fabriquer des nanostructures sur demande. Chaque fois que nécessaire, ces structures seront modifiées localement (en surface ou non) par des réactions chimiques capables de leur conférer des propriétés spécifiques (magnétiques, électriques, possibilité de reconnaissance spécifique et de détection,…). Les fonctions spécifiques de ces nano-objets seront testées, comme telles ou comme parties intégrantes d'assemblages bi- et tri-dimensionnels. La même démarche générale sera appliquée à la modification et fonctionnalisation de surfaces. L'effort de fonctionnalisation de matériaux polymères multicomposés/multiphasés sera également poursuivi.

Finalement, la recherche sera dirigée vers la modification de surface de biomatériaux et l'étude de leur interaction avec des cellules et des protéines. La croissance des cellules sur ces surfaces sera également guidée par des chemins imprimés sur celles-ci (patterning) par micro- ou nanotechnologie. Recevront une attention particulière, des polymères taillés sur mesure en vue de l'ingéniérie tissulaire, des polymères biodégradables, des hydrogels, des composites polymères, des systèmes biocéramiques et des molécules bioactives. Des polymères cationiques vecteurs en thérapie génique, des assemblages supramoléculaires par complexation de polyélectrolytes, des marqueurs spécifiques du DNA, la technologie des membranes incluant l'arrimage moléculaire ("molecular docking") seront étudiés et développés en interaction étroite avec les autres tâches.

Documentation :

Références bibliographiques :

"In situ" formation of yttrium alkoxides : a versatile and efficient catalyst for the ROP of ?-caprolactone  MARTIN, Ph. DUBOIS, R. JÉRÔME. Macromolecules, 36, 2003 

?-conjugated Oligo-(p-phenylenevinylene) Rosettes and their tubular Self Assembly. Angew.Chem.Int.Ed., 43, 74-78  JONKHEIJM P., A. MIURA, M. ZDANOWSKA, F.J.M. HOEBEN, S. DE FEYTER, A.P.H.J. SCHENNING, F.C. DE SCHRYVER, E.W. MEIJER. Angew.Chem. 116, 2003 

2,7-Bis(diarylamino)-9,9-dimethylfluorenes as Hole-Transport Materials for Organic Light-Emitting Diodes.  HREHA R.D., C. P. GEORGE, A. HALDI, B. DOMERCQ, M. MALAGOLI, S. BARLOW, J.L. BRÉDAS, B. KIPPELEN, S. MARDER. Advanced Functional Materials, 13, 2003 

A comparison of the NMR enantiodifferentiation of a chiral Ru(II) complex of C2 symmetry using the TRISPHAT anion and a lanthanide shift reagent.  BRUYLANTS, C. BRESSON, A. BOISDENGHIEN, F. PIERARD, A. KIRSCH – DE MESMAEKER, J. LACOUR, K. BARTIK. New J. Chem. 27, 2003 

A convenient procedure for the synthesis of tetrathia-7]-helicene and the selective alpha-functionalisation of terminal thiophene ring.  MAIORANA, S; PAPAGNI, A; LICANDRO, E; ANNUNZIATA, R; PARAVIDINO, P; PERDICCHIA, D; GIANNINI, C; BENCINI, M; CLAYS, K; PERSOONS, A Tetrahedron 59 (34), 2003 

A joint theoretical and experimental study on the electronic properties of phenyl-capped 3,4-ethylenedioxythiophene oligomers.  OSIKOWICZ W., A.W. DENIER VAN DER GON, X. CRISPIN, M. DE JONG, R. FRIEDLEIN, L. GROENENDAAL, M. FAHLMAN, D. BELJONNE, R. LAZZARONI, W.R. SALANECK. Journal of Chemical Physics, 119, 2003 

A Molecular Dynamics Study of ?-Caprolactone Intercalated in Wyoming Sodium Montmorillonite.  GAUDEL-SIRI, P. BROCORENS, D. SIRI, F. GARDEBIEN, J.L. BRÉDAS, and R. LAZZARONI. Langmuir, 19, 2003 

A novel catalytic filter for tar removal from biomass gasifcation gas: Improvement of the catalytic activity in presence of H2S,  ENGELEN K., Y. ZHANG, D. J. DRAELANTS, G. V. BARON, Chem. Eng. Sci., 58, 2003 

A Novel Correlation for the Pressure Drop in Monolithic Silica Columns.  VERVOORT, N., GZIL, P., BARON, G. V. and DESMET, G., Analytical Chemistry 75, 2003 

A simplified partial ionic charge model tevaluate the role played by bismuth pyrostannate in multiphase catalysts for the selective oxidation of isobutene tmethacrolein.  MOENS L., P. RUIZ, B. DELMON, M. DEVILLERS. Applied Catal. A:General 249, 2003 

A Zeolite-Enzyme Combination for Biphasic Dynamic Kinetic Resolution of Benzylic Alcohols.  WUYTS S., DE TEMMERMAN K., DE VOS D.E., and JACOBS P.A. Chem. Commun., 2003 

A. Molecular quadratic non-linear optical properties of dipolar trans-tetraammineruthenium(II) complexes with pyridinium and thiocyanate ligands  COE, BJ; JONES, LA; HARRIS, JA; SANDERSON, EE; BRUNSCHWIG, BS; ASSELBERGHS, I; CLAYS, K; PERSOONS, A. Dalton Transactions 11, 2003 

A. Second-order nonlinear optical properties of nanocrystalline maghemite particles.  GALLET, S; VERBIEST, T; PERSOONS, A. Chemical Physics Letters 378 (1-2), 2003 

Ab initicalculations of doubly resonant sum-frequency generation second-order polarizability of LiH.  ZALESNY R., W. BARTKOWIAK, B. CHAMPAGNE. Chem. Phys. Letters 380, 2003 

Absorption and Emission in Quaterthienyl Thin Films.  SUN H., Z. ZHAO, F.C. SPANO, D. BELJONNE, J. CORNIL, Z. SHUAI, and J.L. BRÉDAS. Advanced Materials, 15, 2003 

Acidic properties of a clay prepared from the reaction of zirconyl chloride solution containing sulfate ions with montmorillonite.  EN CHAABENE S., L. BERGAOUI, A. GHORBEL, J.F. LAMBERT, P. GRANGE. Appl. Catal. A: General 252, 2003 

Activation of Hydrogen Peroxide through Hydrogen-Bonding Interaction with Acidic Alcohols: Epoxidation of Alkenes in Phenol.  WAHLEN J., DE VOS D.E., and JACOBS P.A. Organic Letters, 5, 2003 

Activity in methane combustion and sensitivity tsulfur poisoning of La1-xCexMn1-yCoyO3 perovskite oxides  ALIFANTI M., R. AUER, J. KIRCHNEROVA, F. THYRION, P. GRANGE, B. DELMON. Appl. Catal. B:Environmental 41, 2003 

Adlayers and low-dimensional assemblies of a TTF derivative at a liquid-solid interface.  ABDEL-MOTTALEB M.M.S., E. GOMAR-NADAL, S. DE FEYTER, M. ZDANOWSKA, J. VECIANA, C. ROVIRA, D.B. AMABILINO, F.C. DE SCHRYVER. NanLetters, 3, 10,, 2003 

Adsorption competition effects in hydroconversion of alkane mixtures on zeolites,  DENAYER J.F.M., Refik OCAKOGLU, BrunDE JONCKHEERE, Johan A. MARTENS, Joris W. THYBAUT, Guy B. MARIN GinV. BARON. Int. J. Chem. React. Eng. 1 A36, 2003 

Adsorption competition effects in hydroconversion of alkane mixtures on zeolites,  DENAYER, J.F.M., OCAKOGLU, R.A., De JONCKHEERE, B., MARTENS, J.A., THYBAUT, J.W., MARIN, G.B., BARON, G.V. Int. J. Chem. React. Eng., 1, A36, 2003 

Adsorption of Polyethylene Standards from Decalin on Liquid Chromatography Column Packings,  MACKO, T., PASCH, H., DENAYER, J.F.M. J. Chromatography A, 1002, 2003 

Advances in propane ammoxidation catalyst technology Oil Gas  PRADA SILVY R. And P. GRANGE European Magazine 3, 2003 

Advantages of Perfectly Ordered 2-D Porous Pillar Arrays over Packed Bed Columns for LC Separations: A Theoretical Analysis.  GZIL, P.; VERVOORT, N.; BARON, G. V.; DESMET, G. Analytical Chemistry 75(22), 2003 

Aggregation of yeasts cells : direct measurement of discrete lectin-carbohydrate interactions.  TOUHAMI, A., HOFFMANN, B., VASELLA, A., DENIS, F.A. and DUFRÊNE, Y.F. Microbiology 149, 2003 

Alternating Oligo(p-phenylene vinylene)-perylene bisimide copolymers: Synthesis, Photophysics, and Photovoltaic Properties of a New Class of Donor-Acceptor Materials  NEUTEBOOM E.E., S.C.J. MESKERS, P.A. VAN HAL, J.K.J. VAN DUREN, E.W. MEIJER, R.A.J. JANSSEN, H. DUPIN, G. POURTOIS, J. CORNIL, R. LAZZARONI, J.L. BRÉDAS, and D. BELJONNE. Journal of the American Chemical Society, 125, 2003 

Amphiphilic copolymers of ?-caprolactone and ?-substituted ?-caprolactone. Synthesis and functionalization of poly(D,L-lactide) nanoparticles.  GAUTIER S., V. D'ALOIA, O. HALLEUX, M. MAZZA, Ph. LECOMTE, R. JÉRÔME. J. Biomater. Sci. Polymer Edn, 14, 2003 

An Anionic Organic Mixed-Valence System with a Remarkable Well-Resolved Vibrational Structure in its Intervalence Band.  RISKO, S. BARLOW, V. COROPCEANU, M. HALIK, J.L. BRÉDAS, and S. MARDER. Chemical Communications, 2, 2003 

An attempt texplain the role of CO2 and N2as gas dopes in the feed in the oxidative dehydrogenation of propane. Role of dissociative species during the reaction.  DURY F., M. A. CENTENO, E. M. GAIGNEAUX, and P. RUIZ. Catalysis Today, 81 (2003) 95-105, 2003 

An energy transfer study of homopolymer localization in block copolymers.  RHARBI Y., J. ZHANG, J.G. SPIRO, L. CHEN, M.A. WINNIK, J.D. VAVASOUR, M.D. WHITMORE, R. JÉRÔME. Macromolecules, 36, 2003 

An OperandOptical Fiber UV-vis Spectroscopic Study of the Catalytic Decomposition of Nand N2over Cu-ZSM-5.  GROOTHAERT, M., LIEVENS, K., WECKHUYSEN, B. M., and SCHOONHEYDT, R. A. J.Catal., 220, 2003 

Analytical time-dependent Hartree-Fock evaluation of the dynamic zero-point vibrationally averaged (ZPVA) first hyperpolarizability.  QUINET O., B. KIRTMAN, B. CHAMPAGNE. J. Chem. Phys. 118, 2003 

Assessment of the Reliability of the Perdew-Burke-Ernzerhof in the Determination of Torsional Potentials in ?-Conjugated Molecules.  SANCHO-GARCIA J.C., J. CORNIL, and J.L. BRÉDAS. Chemical Physics Letters, 377, 2003 

Asymmetrically protected porphyrin meso-tetraphenols and their application in the synthesis of pentaporphyrin dendrimers.  SMEETS S., H. ROEX, W. DEHAEN. ARKIVOC, IV, 2003 

Atomic force microscopy provides a new means for looking at microbial cells  DUFRÊNE, Y.F. ASM News 2003, 69, 2003 

b InitiStudy of the Adsorption of the Butene Isomers in Faujasite  TIELENS, F., DENAYER, J., DAEMS, I., BARON, G.V., MORTIER, W.J., GEERLINGS, P. J. Phys. Chem B., 107, 2003 

Bias-dependent visualisation of electron donor (D) and electron acceptor (A) moieties in a chiral DAD triad molecule.  MIURA, Z. CHEN, S. DE FEYTER, M. ZDANOWSKA, H. UJI-I, P. JONKHEIJM, A.P.H.J. SCHENNING, E.W. MEIJER, F. WÜRTHER, F.C. DE SCHRYVER. J.Am.Chem.Soc, 125 (49), 2003 

Biodegradable compositions by reactive processing of aliphatic polyester/ polysaccharide blends  DUBOIS Ph., NARAYAN R. Macromol. Symp., 198(1), 2003 

Biodegradation of poly(?-caprolactone)/starch blends and composites in composting and culture environments: the effect of compatibilization on the inherent biodegradability of the host polymer.  SINGH R.P., PANDEY J.K., RUTOT D., DEGEE Ph., DUBOIS Ph. Carbohydrate Research, 338, 2003 

Bioresorbable and bioactive composite materials based on polylactide foams filled with and coated by Bioglass particles for tissue engineering applications  BOCCACCINI A.R., I. NOTINGHER, V. MAQUET, R. JÉRÔME. Journal of Materials Science: Materials in Medicine, 14(5), 2003 

Bis (?-oxo)dicopper in Cu-ZSM-5 and its Role in the Decomposition of NO: a Combined in situ XAFS, UV-vis-NIR and Kinetic Study  GROOTHAERT M., VAN BOKHOVEN J., BATTISTON A., WECKHUYSEN B.M., and SCHOONHEYDT R.A. J. Am. Chem. Soc., 125, 2003 

Bis(dioxaborine) Compounds with Large Two-Photon Cross Sections, and Their Use in the Photodeposition of Silver.  HALIK M., W. WENSELEERS, C. GRASSO, F. STELLACCI, E. ZOJER, S. BARLOW, J.L. BRÉDAS, J.W. PERRY, and S.R. MARDER. Chemical Communications, 13,, 2003 

Block copolymers of methyl vinyl ether and isobutyl vinyl ether with thermo-adjustable amphiphilic properties.  VERDONCK, E. GOETHALS, F.E. DU PREZ. Macromol. Chem. Phys., 204, 2003 

Catalytic application of a Ru-alkylidene in the nucleophilic addition of several carboxylic acids on terminal alkynes and the homocoupling of 1-alkynes  MELIS K, DE VOS D, JACOBS P, VERPOORT F. J. Organometal. Chem., 671 (1-2), 2003 

Characterization of a novel intracellular endopeptidase of the ?/? hydrolase family from Streptomyces coelicolor A3(2).  NAGY I, BANERJEE T, TAMURA T, SCHOOFS G, GILS A, PROOST P, TAMURA N, BAUMEISTER W and DE MOT R. J. Bacteriol. 185, 496-503., 2003 

Characterization of CeO2-ZrO2 mixed oxides. Comparison of the citrate and sol-gel preparation methods  ALIFANTI M., B. BAPS, N. BLANGENOIS, J. NAUD, P. GRANGE And B. DELMON Chem. Mater. 15, 2003 

Characterization of genes involved in poly-?-hydroxybutyrate metabolism in Azospirillum brasilense.  EDELSTEIN Z, KADOURI D, JURKEVITCH E, VANDE BROEK A, VANDERLEYDEN J and OKON Y. Symbiosis 34., 2003 

Charge transfer complex inimer : a facile route tdendritic materials.  WANG W., D. YAN, D. BRATTON, S.M. HOWDLE, Q. WANG, Ph. LECOMTE. Advanced Materials, 15, 2003 

Charge-Transfer Transitions in Triarylamine Mixed-Valence Systems: The Effect of Temperature.  COROPCEANU V., C. LAMBERT, G. NÖLL, and J.L. BRÉDAS. Chemical Physics Letters, 373,, 2003 

Chemoselective oxidation of 2-thiomethyl-4,6-dimethyl-pyrimidine and 2-thiobenzyl-4,6-dimethyl-pyrimidine over titania-silica catalysts.  RADU D.C., V.I. PARVULESCU, V. CAMPEANU, E. BARTHA, A. JONAS And P. GRANGE. Appl. Catal. A: General 242, 2003 

Cloning and heterologous expression of a ?-D-mannosidase encoding gene from Thermobifida fusca TM51.  BÉKI E, NAGY I, VANDERLEYDEN J, JÄGER S, KISS L, FÜLÖP L, HORNOK L and KUKOLYA J. Appl. Environ. Microbiol. 69,, 2003 

Co-Immobilisation of Transition Metal Complexes and Ionic Liquids in a Polymeric Support for Liquid Phase Hydrogenations.  WOLFSON A., VANKELECOM I.F.J., and JACOBS P.A. Tetrah. Lett., 44, 2003 

Combinatorial Screening tConventional Testing of Antimony Rich Selective Oxidation Catalysts.  PAUL, J., URSCHEY, J., JACOBS, P. A., MAIER, W. F., and VERPOORT, F. J.Catal., 220, 2003 

Combining ATRP of methacrylates and ROP of ?-caprolactone.  YDENS I., DEGEE Ph., DUBOIS Ph., LIBISZOWSKI J., DUDA A., PENCZEK St. Macromol. Chem. Phys., 204, 2003 

Comparison of Hexamethylhypericin and Tetrabromohypericin tHypericin for their in vivefficacy as PDT Tools.  DELAEY E., ZUPKÓ I., CHEN B., DERYCKE A., VAN LAAR F., DE VOS D.E., and DE WITTE P. Int. J. Oncol., 23,, 2003 

Complexation of uranyl ions by polypyrrole doped by sulfonated and phosphonated polyethyleneimine.  LEROY, L. MARTINOT, P. MIGNONSIN, D. STRIVAY, G. WEBER, C. JÉRÔME, R. JÉRÔME. J. Applied Polym. Sci., 88, 2003 

Computational Fluid Dynamics Simulations Yielding Guidelines for the Ideal Internal Structure of Monolithic LC Columns.  GZIL, P., BARON, G. V. and DESMET, G. Journal of Chromatography A 991, 2003 

Conductivity, Morphology, Interfacial Chemistry and Stability of Poly(3,4-ethylenedioxythiophene)-polystyrenesulfonate (PEDT/PSS): a Photoelectron Spectroscopy Study  CRISPIN X., S. MARCINIAK, W. OSIKOWICZ, G. ZOTTI, A.W. DENIER VAN DER GON, F. LOUWET, M. FAHLMAN, L. GROENENDAAL, F.C. DE SCHRYVER, W.R. SALANECK. J. Polym. Sci. Part B : Polymer Physics, 41, 2003 

Confocal fluorescence microscopy and AFM of Thiacyanine J Aggregates in Langmuir-Schaefer monolayers  CHUN-HONG Tian, G. ZORINIANTS, R. GRONHEID, M. VAN DER AUWERAER, F.C. DE SCHRYVER. Langmuir, 19 (23), 2003 

Conformation change of albumin adsorbed on polycarbonate membranes as revealed by ToF-SIMS  HENRY, M., DUPONT-GILLAIN, C. and BERTRAND, P. Langmuir 19, 2003 

Conjugated Material Self-assembly: Towards Supramolecular Electronics.  LECLÈRE Ph., M. SURIN, M. CAVALLINI, P. JONKHEIJM, O. HENZE, A.P.H.J. SCHENNING, F. BISCARINI, A.C. GRIMSDALE, W.J. FEAST, E.W. MEIJER, K. MÜLLEN, J.L. BRÉDAS, and. R. LAZZARONI. Transactions of the Materials Research Society of Japan, 29, 2003 

Constraints on detection of autoinducer-2 (AI-2) signaling molecules using Vibriharveyi as a reporter.  DE KEERSMAECKER SCJ, and VANDERLEYDEN J. Microbiology 149(8),, 2003 

Contolled patterning of biomolecules on solid surfaces.  MARTELÉ Y., K. CALLEWAERT, K. NAESSENS, P. VAN DAELE, R. BAETRS & E. SCHACHT. Materials Science and Engineering C23, 2003 

Controlled Free Radical Polymerization of Styrene Initiated from Alkoxyamine Attached tPolyacrylate Chemisorbed ontConducting Surfaces.  VOCCIA S., C. JEROME, C. DETREMBLEUR, Ph. LECLERE, R. GOUTTEBARON, M. HECQ, B. GILBERT, R. LAZZARONI, R. JEROME. Langmuir, 15, 2003 

Controlled free radical polymerization of styrene initiated from alkoxyamine attached tpolyacrylate chemisorbed ontconducting surfaces.  VOCCIA S., C. JÉRÔME, C. DETREMBLEUR, Ph. LECLÈRE, R. GOUTTEBARON, M. HECQ, B. GILBERT, R. LAZZARONI, R. JÉRÔME. Chem. Mater. 15,, 2003 

Controlled radical polymerization of alkyl methacrylates in the presence of NO/NO2 mixtures.  DETREMBLEUR Ch., M. CLAES, R. JÉRÔME. ACS Symposium Series, 854, 2003 

Controlled synthesis of amphiphilic polymethacrylate-graft-poly(ester)/poly(ether)] graft copolymers; A.C.S.  YDENS I., DEGEE Ph., LIBISZOWSKI J., DUDA A., PENCZEK St., DUBOIS Ph. Symp. Ser. 854, 2003 

Copolymerization effects upon the second-order NLresponses of polyacetylene/polymethineimine.  JACQUEMIN D., B. CHAMPAGNE, J.M.André. Macromolecules 36, 2003 

Coupled-Cluster Approach for Studying the Optical Properties of Charged ?-Conjugated Oligomers.  YE, Z. SHUAI, D. BELJONNE, and J.L. BRÉDAS. Synthetic Metals, 137, 2003 

CrIII(salen) Catalysed Asymmetric Ring Opening of Monocyclic Terpene-Epoxides.  DIOOS B. and JACOBS P.A. Tetrah. Lett., 44, 2003 

Crosslinked polyurethane-based gels.  PHUNG H., E. SCHACHT, F. DU PREZ, J. GELAN, P. ADRIAENSENS, L. STORME. Polymer Journal 34(4), 2003 

De Mesmaeker. Synthesis and characterization of optically active and racemic forms of cyclometalated Rh(III) complexes. An experimental and theoretical emission study  GHIZDAVU L., O. LENTZEN, S. SCHUMM , A. BRODKORB, , C. MOUCHERON and A. KIRSCH - Inorg. Chem., 42, 2003 

Decane Hydroconversion on bifunctional Zeogrid and NanZeolite Assembled from Aluminosilicate Nanoslabs of MFI Framework Type  ERTS Alexander, Annabel VAN ISACKER, Ward HUYBRECHTS, Sebastien P.B. KREMER, Christine E.A. KIRSCHHOCK, François COLLIGNON, Kristof HOUTHOOFD, Joeri F.M. DENAYER, GinV. BARON, Guy B. MARIN, Pierre A. JACOBS and Johan A. MARTENS. Appl. Catal. A.-Gen 257, 2003 

Density Functional Theory Analysis of Benzene (De)hydrogenation on Pt(111): Addition and Removal of the first twH-atoms,  SAEYS Mark, Marie-Françoise REYNIERS, Matthew NEUROCK and Guy B. MARIN. J. Phys. Chem. B 107, 2003 

Density Functional Theory and Hartree-Fock Studies of the Geometric and Electronic Structure of Neutral and Doped Ethylenedioxythiophene (EDOT) Oligomers.  DKHISSI, D. BELJONNE, R. LAZZARONI, F. LOUWET, L. GROENENDAAL, and J.L. BRÉDAS. International Journal of Quantum Chemistry, 91, 2003 

Dependence of the interfacial reaction and morphology development on the functionality of the reactive precursors in reactive blending.  YIN Z., C. KOULIC, C. PAGNOULLE, R. JÉRÔME. Macromol. Symp., 198, 2003 

Desorption behaviour of regular adsorbed polyampholytic layers.  MAHLTIG, J.F. GOHY, R. JÉRÔME, G. PFUETZE, M. STAMM. J. Polymer Research, 10(2), 2003 

Determination of DNA guanine sites forming photo-adducts with Ru-labelled oligonucleotides. DNA polymerase inhibition by the resulting photo-crosslinking.  LENTZEN, E. DEFRANCQ , J.F. CONSTANT, S. SCHUMM, D. GARCIA-FRESNADILLO, C. MOUCHERON, P. DUMY, A. KIRSCH – DE MESMAEKER. J. Biol. Inorg. Chem., 2003 

Determination of polyisoprene-block-poly(methyl methacrylate) domain sizes using 1H spin diffusion.  WERKHOVEN T.M., F.M. MULDER, C. ZUNE, R. JÉRÔME, H.J.M. DE GROOT. Macromol. Chem. & Phys., 204, 2003 

Determination of the local cross-link density in polyisobutylene-based elastomers by NMR Imaging.  ADRIAENSENS P., A. POLLARIS, M. KELCHTERMANS and J. GELAN. Macromolecules, 36, 2003 

Development of a Catalytic Candle Filter for One-Step Tar and Particle Removal in Biomass Gasification Ga  ENGELEN Karen, YUHONG Zhang, and GinV. BARON International Journal of Chemical Reactor Engineering, 1, A29,, 2003 

Development of a Fixed-Bed Continuous-Flow High-Throughput Reactor for Long-Chain n-Alkane Hydroconversion.  HUYBRECHTS W., MIJOIN J., JACOBS P.A., and MARTENS J.A. App. Catal. A-Gen., 243, 2003 

DFT Study on the Electrophilic Aromatic Substitution Catalyzed by Lewis Acids.  VOS, A., SCHOONHEYDT, R. A., DE PROFT, F., and GEERLINGS, P. J.Catal., 220, 2003 

Diffusion-Reaction Modelling of DNA Hybridization Kinetics on Biochips,  PAPPAERT, K., VAN HUMMELEN, P., VANDERHOEVEN, J., BARON, G. V. and DESMET, G. Chemical Engineering Science 58, 2003 

Direct observation of chiral oligo(p-phenylene vinylene)s with scanning tunneling microscopy  GESQUIÈRE, P. JONKHEIJM, A.P.H.J. SCHENNING, E. MENA-OSTERITZ, P. BÄUERLE, S. DE FEYTER, F.C. DE SCHRYVER, E.W. MEIJER. J. Mat. Chem., 13, 2003 

Direct proof of electron transfer in a rigid first generation triphenyl amine core dendrimer substituted with a peryleneimide acceptor.  LOR M., S. JORDENS, G. DE BELDER, G. SCHWEITZER, E. FRON, L. VIAENE, M. COTLET, T. WEIL, K. MÜLLEN, J.W. VERHOEVEN, M. VAN DER AUWERAER, F.C. DE SCHRYVER. Photochem.& Photophys.Sci.,2, 2003 

Dynamic Force Microscopy Analysis of Nanocomposites, Polymer Blends, and Block Copolymers: Beyond Imaging the Surface Morphology.  LECLERE Ph., F. DUBOURG, P. VIVILLE, V. CORNET, J.P. AIME, and R. LAZZARONI. Polymeric Materials Science & Engineering (PMSE) Preprints, 88, 2003 

Effect of an External Electric Field on the Charge Transport Parameters in Molecular Organic Semiconductors.  SANCHO-GARCIA J.C., G. HOROWITZ, J.L. BRÉDAS, and J. CORNIL Journal of Chemical Physics, 119,, 2003 

Effect of pressure and temperature upon tin alkoxide-promoted ring-opening polymerisation of ?-caprolactone in supercritical carbon dioxide.  STASSIN F., R. JÉRÔME. ChemComm 232-233, 2003 

Effect of Substitution on the Hole Mobility of Bis(diarylamino)biphenyl Derivatives Doped in Poly(Styrene)  MADONADJ.L., M. BISHOP, C. FUENTES-HERNANDEZ, P. CARON, B. DOMERCQ, Y.D. ZHANG, S. BARLOW, S. THAYUMANAVAN, M. MALAGOLI, J.L. BRÉDAS, S.R. MARDER, and B. KIPPELEN. Chemistry of Materials, 15, 2003 

Effective molecular polarizabilities and hyperpolarizabilities in all-trans hexatriene clusters.  BOTEK E., B. CHAMPAGNE. Chem. Phys. Lett. 370, 2003 

Electronic and Optical Properties of Polyfluorene and Fluorene-Based Copolymers: A Quantum-Chemical Characterization.  CORNIL J., I. GUELI, A. DKHISSI, J.C. SANCHO-GARCIA, E. HENNEBICQ, J.P. CALBERT, V. LEMAUR, D. BELJONNE, and J.L. BRÉDAS. Journal of Chemical Physics, 118, 2003 

Electrophilic substitution reactions of dipyrroheptane.  DEPRAETERE S., W. DEHAEN. Tetrahedron Lett. 44, 2003 

Energy Transfer in ?-Conjugated Polymers: Interchain vs. Intrachain Processes in Polyindenofluorene.  BELJONNE, G. POURTOIS, Z. SHUAI, E. HENNEBICQ, G.D. SCHOLES, and J.L. BRÉDAS. Synthetic Metals, 137, 2003 

Energy transfer within perylene-terrylene dendrimers evidenced by polychromcatic transient absorption measurements.  JORDENS S., G. DE BELDER, M. LOR, G. SCHWEITZER, M. VAN DER AUWERAER, T. WEIL, E. REUTHER, K. MÜLLEN, F.C. DE SCHRYVER. Photochem. and Photobiol. Science, 3, 2003 

Enhancement of DNA Microarray-analysis Using a Shear-Driven Micro-channel Flow System,  PAPPAERT, K., VANDERHOEVEN, J., DUTTA, B., VAN HUMMELEN, P., CLICQ, D., BARON, G. V. and DESMET, G; Journal of Chromatography A 1014, 2003 

EVA-layered silicate/carbon nanotubes nanocomposites.  PEETERBROECK S., ALEXANDRE M., B.NAGY J., PIRLOT C., FONSECA A., PHILIPPIN G., DELHALLE J., MEKHALIF Z., SPORKEN R., BEYER G., DUBOIS Ph. Eurofillers’03 proceedings., 2003 

Excimer laser induced patterning of polymeric surfaces.  CALLEWAERT K., Y. MARTELÉ, L. BREBAN, K. NAESSENS, P. VANDAELE, R. BAETS, G. GEUSKENS & E. SCHACHT. Applied Surface Science 208-209, 2003 

Excited state processes in individual multichromophoric systems1.  HOFKENS J., T. VOSCH, M. COTLET, S. HABUCHI, K. VAN DER BIEST, K. MÜLLEN, G. DIRIX, J. MICHIELS, J. VANDERLEYDEN, M. SAUER, F.C. DE SCHRYVER. Proceedings of SPIE, vol. 4962, 2003 

Exfoliated polylactide/clay nanocomposites by in-situ coordination-insertion polymerization.  PAUL M.A., M. ALEXANDRE, Ph. DEGEE, C. CALBERG, R. JEROME, Ph. DUBOIS. Macromol. Rapid. Commun., 24, 2003 

Experimental study of the second-order non-linear optical properties of tetrathia-7]-helicene.  CLAYS, K; WOSTYN, K; PERSOONS, A; STEFANO, MB; MAIORANA, S; PAPAGNI, A; DAUL, CA; WEBER, V. Chemical Physics Letters 372 (3-4), 2003 

Experimental van Deemter-plot of Shear-Driven LC Separations in Disposable Micro-channels.  VERVOORT, N., CLICQ, D., BARON, G. V. and DESMET, G. Journal of Chromatography A 987, 2003 

Extraction procedure for sulfachloropyridazine in porcine tissues and detection in a sulfonamide-specific enzyme-linked immunosorbent assay (ELISA).  CLIQUET P., E. COX, W. HAASNOOT, E. SCHACHT & B.M. GODDEERIS. Analytica Chemica Acta 494, 2003 

Fluorescence and intramolecular energy transfer in polyphenylene dendrimers.  LIU D., S. DE FEYTER, M. COTLET, A. STEFAN, U-M. WIESLER, A. HERRMANN, D. GREBEL-KOEHLER, K. MÜLLEN, F.C. DE SCHRYVER. Macromolecules, 36, nr 16, 2003 

Fluorescent self-assembled polyphenylene dendrimer nanofibers  LIU D., S. DE FEYTER, M. COTLET, U-M. WIESLER, T. WEIL, A. HERRMANN, K. MÜLLEN, F.C. DE SCHRYVER. Macromolecules, 36, 2003 

From ‘Sunflower-like’ Assemblies toward Giant Wormlike Micelles.  BORSALI R., E. MINATTI, J.L. PUTAUX, M. SCHAPPACHER, A. DEFFIEUX, P. VIVILLE, R. LAZZARONI, T. NARAYANAN. Langmuir, 19, 2003 

Fully quantitative carbon-13 NMR characterization of resol phenol-formaldehyde prepolymer resins.  REGR., P.J. ADRIAENSENS, R.A. CARLEER and J.M. GELAN. Polymer, 45, 2003 

Functional segmented polymer networks based on poly(tetrahydrofuran) and poly(vinylbenzyl chloride).  JONCKHEERE L., E. GOETHALS, F. DU PREZ. E-Polymers 64, 2003 

Generation dependent Singlet-Singlet Annihilation within multichromophoric dendrimers studied by Polychromatic transient absorption.  JORDENS S., G. DE BELDER, M. LOR, G. SCHWEITZER, M. VAN DER AUWERAER, T. WEIL, A. HERRMANN, U.-M. WIESLER, K. MÜLLEN, F.C. DE SCHRYVER. Photochem. & Photobiol. Sci., 2, 2003 

Generation of group-specific antibodies against sulfonamides.  CLIQUET P., COX E., HAASNOOT W., SCHACHT E. and GODDEERIS B. Journal of Agricultural and Food Chemistry 51(20), 2003 

Geometric and Electronic Structure of Zwitterionic Push-Pull Polyenes for Nonlinear Optics  GESKIN V.M. and J.L. BRÉDAS. International Journal of Quantum Chemistry, 91, 2003 

Growth of ultrathin Ti films deposited on SnO2 by magnetron sputtering.  GODFROID T., R. GOUTTEBARON, J.P. DAUCHOT, Ph. LECLÈRE, R. LAZZARONI, M. HECQ. Thin Solid Films, 437, 2003 

H- and thermo-responsive properties of poly(N-vinylcaprolactam-co-acrylic acid) copolymers.  SHTANKN.I., W. LEQUIEU, E.J. GOETHALS, F.E. DU PREZ. Polym. Int., 52, 2003 

High glass transition temperature chromophore functionalised poly(phenylquinoxalines) for nonlinear optics.  GUBBELMANS, E; VAN DEN BROECK, K; VERBIEST, T; VAN BEYLEN, M; PERSOONS, A; SAMYN, C. European Polymer Journal 39 (5), 2003 

High Pressure Liquid Phase Hydroconversion of Heptane/Nonane Mixture on Pt/H-Y Zeolite Catalyst,  DENAYER, J.F.M., OCAKOGLU, R.A., HUYBRECHTS, W., DEJONCKHEERE, B., MARTENS, J.A., JACOBS, P.A., CALERO, S., KRISHNA, R., SMIT, B. and BARON, G.V. J. Catal., 220,, 2003 

High Temperature Adsorption of n-Alkanes on ZSM-5 Zeolites: Influence of the Si/Al ratiand the synthesis method  ARIK, I.C., DENAYER, J.F.M., BARON, G.V., Microporous and Mesoporous Materials, 60 (1-3), 2003 

Highly unusual effects of pi-conjugation extension on the molecular linear and quadratic nonlinear optical properties of ruthenium(II) ammine complexes.  COE, BJ; JONES, LA; HARRIS, JA; BRUNSCHWIG, BS; ASSELBERGHS, I; CLAYS, K; PERSOONS, A. Journal Of The American Chemical Society 125 (4), 2003 

Host matrix dependence on the photophysical properties of individual conjugated polymer chains  SARZI S.; SARTORI, S. DE FEYTER, J. HOFKENS, M. VAN DER AUWERAER, F.C. DE SCHRYVER, K. BRUNNER, J.W. HOFSTRAAT. Macromolecules, 36(2), 2003 

Hydrolytic and thermal degradation of random copolyesters of e-caprolactone and 2-oxepane –1,5-dione.  LATERE J.P., Ph. LECOMTE, Ph. DUBOIS, R. JÉRÔME. Macromol. Chem. Phys. 204, 2003 

Identification and quantification of polymerization defects in 13C-labeled sulphinyl and Gilch OC1C10-PPV by NMR spectroscopy.  ROEX H., P. ADRIAENSENS, D. VANDERZANDE and J. GELAN. Macromolecules, 36, 2003 

Identification of a third sulfate activation system in Sinorhizobium sp. strain BR816: the CysDN sulfate activation complex  SNOECK C, VERRETH C, HERNÁNDEZ-LUCAS I, MARTÍNEZ-ROMERE, and VANDERLEYDEN J. Appl. Environm. Microbiol. 69, 2006-2014., 2003 

Identification of free radicals trapped in solid methacrylated resins.  TRUFFIER-BOUTRY, D., GALLEZ, X.A., DEMOUSTIER-CHAMPAGNE, S., DEVAUX, J., DEBATTY-MESTDAGH, M., CHAMPAGNE, B., LELOUP, G. Journal of Polymer Science : Part A : Polymer Chemistry , 41(11), 2003 

Image analysis of the axonal ingrowth intpoly(D,L-lactide) porous scaffolds in relation tthe 3-D porous structure.  BLACHER S, MAQUET V, SCHILS F, MARTIN D, SCHOENEN J, MOONEN G, JEROME R, PIRARD J-P. Biomaterials, 24(6), 2003 

Immobilisation of glucose oxydase on metallic nanotubes arrays for application tglucose biosensor.  DELVAUX, M., DEMOUSTIER-CHAMPAGNE, S. Biosensors and Bioelectronics 18, 2003 

Immobilization of silver in polypyrrole/polyanion composite coatings : preparation, characterization and antibacterial activity.  IGNATOVA M., D.E. LABAYE, S. LENOIR, D. STRIVAY, R. JEROME, C. JEROME. Langmuir, 19, 2003 

Impact of Silicone-Based Block Copolymer Surfactants on the Surface and Bulk Microscopic Organization of a Biodegradable Polymer, Poly(-caprolactone).  VIVILLE P., R. LAZZARONI, P. DUBOIS, A. KOTZEV, Y. GEERTS, G. BORCIA, J.J. PIREAUX. Biomacromolecules, 4, 2003 

Improved quantitative solution state 13C NMR analysis of ethylene-1-octene copolymers.  ADRIAENSENS P.J., F.G. KARSSENBERG, J. M. GELAN and V.B.F. MATHOT. Polymer, 44, 2003 

Improvement of Sulphur Resistance of a Nickel-modified Catalytic Filter for Tar Removal from Biomass Gasification Gas,  ZHANG, Y., DRAELANTS, D.J., ENGELEN, K., BARON, G.V. J Chem Technol Biotechnol, 78, 2003 

Improvement of Sulphur Resistance of a Nickel-modified Catalytic Filter for Tar Removal from Biomass Gasification Gas,  ZHANG, Y., DRAELANTS, D.J., ENGELEN, K., BARON, G.V. Proceedings 5th International Symposium on Gas Cleaning at High Temperature, CD Edition, 2003, 2003 

In situ formation of Y alkoxides: a versatile and efficient catalyst for the ROP of ?-caprolactone;  MARTIN E., DUBOIS Ph., JÉRÔME R. Macromolecules, 36, 2003 

In situ investigation of dynamical nano-phase separation.  ABDEL-MOTTALEB MMS, S. DE FEYTER, M. SIEFFERT, M. KLAPPER, K. MÜLLEN, F.C. DE SCHRYVER Langmuir, 19 (20),, 2003 

In situ reversible electrochemical switching of the molecular first hyperpolarizability.  ASSELBERGHS, I; CLAYS, K; PERSOONS, A; MCDONAGH, AM; WARD, MD; MCCLEVERTY, JA Chemical Physics Letters 368 (3-4), 2003 

Influence of the reaction conditions on the activity properties of vanadium-aluminium oxynitride propane ammoxidation catalyst.  FLOREA M., R. PRADA SILVY, P. GRANGE. Appl. Catal. A:General 255, 2003 

Influence of the zeolite composition on the hydro-isomerisation and hydrocracking of alkanes on Pt/USY zeolites: Modelling of the reaction kinetics using an adsorption-reaction approach  DENAYER, J.F.M., THYBAUT, J.W., MARIN, G.B., MARTENS, J.A., BARON, G.V. Appl. Catal. A., 246, 2003 

Influence of the zeolite composition on the hydro-isomerization and hydrocracking of alkanes on Pt/USY zeolites: modelling of the reaction kinetics using an adsorption-reaction approach  DENAYER J.F.M., J. A. MARTENS, P. A. JACOBS, J. W. THYBAUT, G. B. MARIN, G. V. BARON. Appl. Catal. A-Gen. 246, 2003 

Insertion of a two-dimensional cavity inta self-assembled colloidal crystal.  WOSTYN, K; ZHAO, YX; DE SCHAETZEN, G; HELLEMANS, L; MATSUDA, N; CLAYS, K; PERSOONS, A. Langmuir 19 (10), 2003 

Interaction of N2O(as gas dope) with nickel molybdate catalysts during oxidative dehydrogenation of Propane tpropylene.  DURY, M. A. CENTENO, E.M. GAIGNEAUX and P. RUIZ. Appl. Catal. A: General. 247, 2003 

Intercalative polymerization of cyclic esters in layered silicates : thermal vs. catalytic activation;  PANTOUSTIER N., ALEXANDRE M., DEGEE Ph., KUBIES D., JEROME R., HENRIST C., RULMONT A., DUBOIS Ph. Composite Interfaces, 10(4-5), 2003 

Intramolecular directional energy transfer processes in dendrimers containing perylene and terrylene chromophores.  SCHWEITZER G., R. GRONHEID, S. JORDENS, M. LOR, G. DE BELDER, T. WEIL, E. REUTHER, K. MÜLLEN, F.C. DE SCHRYVER. J.Phys.Chem., 107, n18,, 2003 

Intramolecular directional Förster resonance energy transfer at the single molecule level in a dendritic system.  COTLET M., R. GRONHEID, S. HABUCHI, A. STEFAN, A. BARBAFINA, K. MÜLLEN, J. HOFKENS, F.C. DE SCHRYVER. J.Am.Chem.Soc., 125,, 2003 

Investigation of the Permeability and Selectivity of Gases and Volatile Organic Compounds for Polydimethylsiloxane Membranes.  DE BI., VAN LANGENHOVE H., PRUUOST P., DE NEVE J., PIETERS J., VANKELECOM I.F.J., and DICK E. J. Mem. Sci., 215, 2003 

Iron-Polyaniline Interfaces: Implications for Corrosion Protection  FAHLMAN M., X. CRISPIN, J.A.O. SMALLFIELD, R. LAZZARONI, J.L. BREDAS, S. LI, Y. WEI, and A.J. EPSTEIN. Electroactive Polymers for Corrosion Control, Oxford University Press, 2003 

Kinetic Modeling of the Conversion of Complex Hydrocarbon Feedstocks by Acid Catalysts,  Thybaut JORIS W. and Guy B. MARIN. Chem. Eng. Technol., 26, 2003 

Kinetic modelling of pore mouth catalysis in the hydroconversion of n-Octane on Pt-H-ZSM-22  NARASIMHAN C.S. L., J.W.THYBAUT, G.B.MARIN, Pierre A. JACOBS, J.A.MARTENS, J. F. DENAYER, GinV.BARON. J. Catal 220, 2003 

L’Electronique Moléculaire / La Neuroélectronique / L’Electronique Plastique / Fabrication des Nanostructures.  BRÉDAS J.L., J. CORNIL, D. BELJONNE, R. LAZZARONI, and Ph. LECLERE. Les Nanotechnologies, edited by M. Wautelet (Dunod), 2003 

La industria petrolera y sus estrategias clave de competitividad.  PRADA SILVY R. Oil & Gas Journal Latinoamérica, vol 9, n°5, 2003/Sep 

Large off-diagonal contribution tthe second-order optical nonlinearities of ?-shaped molecules  YANG M. and B. CHAMPAGNE. J. Phys. Chem A 107, 2003 

Laser ablation of gold in chloroform solutions of cetyltrimethylammoniumbromide.  MORTIER, T; VERBIEST, T; PERSOONS,A. Chemical Physics Letters 382,, 2003 

Les matériaux semi-conducteurs organiques: Aspects fondamentaux des mécanismes de transport.  CALBERT J.Ph., J. CORNIL, and J.L. BRÉDAS. Chimie Nouvelle, 81, 2003 

Light and STM-tip inducEd formation of one-dimensional and two-dimensional organic nanostructures.  MIURA, S. DE FEYTER, M.M.S. ABDEL-MOTTALEB, A. GESQUIÈRE, P.C.M. GRIM, G. MOESSNER, M. SIEFFERT, M. KLAPPER, K. MÜLLEN, F.C. DE SCHRYVER. Langmuir, 19, 2003 

Light scattering and microcalorimetry studies on aqueous solutions of thermo-responsive PVCL-g-Pecopolymers  VERBRUGGHE S., ANTTI LAUKKANEN, VLADIMIR ASEYEV, HEIKKI TENHU, FRANÇOISE M. WINNIK, FILIP E. DU PREZ. Polymer, 44, 2003 

Light stability of 3,4-ethylenedioxythiophene-based derivatives.  JEURIS K., L. GROENENDAAL, H. VERHEYEN, F. LOUWET, F.C. DE SCHRYVER. Synthetic Metals, 132, 289-295 (2003), 2003 

Low-temperature synthesized aluminosilicates glasses Part IV Modulated DSC study on the effect of particle size of metakaolinite on the production of inorganic polymer glasses  RAHIER, H., DENAYER, J.F., VAN MELE, B. Journal of Material Science, 38, 2003 

Lubrication by charged polymers.  RAVIV U., S. GIASSON, N. KAMPF, J.F. GOHY, R. JEROME, J. KLEIN. Nature, 425, 2003 

Macromolecular carriers for drug targeting.  SCHACHT, K. DE WINNE, K. HOSTE & S. VANSTEENKISTE. , 2003? 

Magnetic-dipole susceptibilities in electric-field induced second-harmonic generation.  SIONCKE, S; VERBIEST, T; PERSOONS, A. Optical Materials 21 (1-3), 2003 

Materials Research Society (MRS) Symposium Proceedings Series Vol. 775 Symposium P:  Editors: C.J. Brinker, Y. Lu, M. Antonietti, C. Bai Self-Assembled Nanostructured Materials”, 2003 

Mathematics in chemical kinetics and engineering: An introduction the special issue dedicated tpapers presented at the MaCKiE-2002 conference.  CONSTALES Denis, Guy B. MARIN, Grégoire NOCOLIS, Roger VAN KEER, Gregory S. YABLONSKY. Chem. Eng. Sci. 58, 2003 

MCM-41 Immobilised Borate Co-Catalyst for Metallocene Catalyzed Propene Oligomerization  KWANTEN M., CARRIÈRE B.A.M., GROBET P.J., and JACOBS P.A. Chem. Commun., 2003 

Mechanistic study of Bu2SnCl2 mediated ring-opening polymerization of ?-caprolactone by multinuclear NMR spectroscopy.  DESHAYES G., MERCIER Fr., DEGEE Ph., VERBRUGGEN I., BIESEMANS M., WILLEM R., DUBOIS Ph. Chem. Eur. J., 9, 2003 

Micellar Morphological Changes Promoted by Cyclization of PS-b-PI Copolymer: DLS and AFM Experiments.  MINATTI, P. VIVILLE, R. BORSALI, M. SCHAPPACHER, A. DEFFIEUX, R. LAZZARONI. Macromolecules, 36, 2003 

Microgravity Effect on the Self-Organization of Silicalite-1 Nanoslabs.  KREMER S.P.B., THEUNISSEN E., KIRSCHHOCK C., JACOBS P.A., MARTENS J.A., and HERFS W. Adv. Space Res., 32, 2003 

Micropatterning polyurethane surfaces with lasers.  MARTELÉ Y., K. NAESSENS, P. VAN DAELE, R. BAETS, K. CALLEWAERT, & E. SCHACHT. Polym Int 52, 2003 

Micro-Raman spectroscopy study of surface transformations induced by excimer laser irradiation of TiO2.  ROBERT T.D., L.D. LAUDE , V.M. GESKIN , R. LAZZARONI, R. GOUTTEBARON. Thin Solid Films, 440, 2003 

Molecular Competition Effects in Liquid Phase Adsorption of Long Chain n-Alkane Mixtures in ZSM-5 Zeolite Pores  DENAYER, J.F.M., DE MEYER, K., MARTENS, J.A., BARON, G.V Angewandte Chemie, 42, 2003 

Molecular Fluorescence Lifetime Fluctuations: On the Possible Role of Conformational Effects.  VALLÉE R.A.L., G.J. VANCSO, N.F. VAN HULST, J.P. CALBERT, J. CORNIL, and J.L. BRÉDAS. Chemical Physics Letters, 372, 2003 

Morphology of protein polymer hibrid films studied by AFM and confocal fluorescence microscopy.  FOUBERT Ph., J.M. HANNINK, F. KÖHN, R. GRONHEID, N. SOMMERDIJK, R. NOLTE, S. DE FEYTER, F.C. DE SCHRYVER. Thin Solid Films, 443/1-2,, 2003 

Mutations in the active site residues Asp-52 and Arg-322 of the Azospirillum brasilense glutamine synthetase differently effect nitrogen regulation  VAN DOMMELEN A, KEIJERS V, WOLLEBRANTS A, and VANDERLEYDEN J. Appl. Environm. Microbiol. 69, 2003 

n-Alkane hydroconversion on Zeogrid and colloidal ZSM-5 assembled from aluminosilicate nanoslabs of MFI framework type.  AERTS Alexander, Ward HUYBRECHTS, Sebastien P.B. KREMER, Christine E.A. KIRSCHHOCK, Liesbeth THEUNISSEN, Annabel VAN ISACKER, Joeri F.M. DENAYER, GinV. BARON, Joris THYBAUT, Guy B. MARIN, Pierre A. JACOBS and Johan A. MARTENS. Chem. Comm. 15, 2003 

Nanocomposites à matrice organique;  ALEXANDRE M., DUBOIS Ph Les Nanotechnologies, edited by M. Wautelet (Dunod), 2003 

Nanoscale mapping of the elasticity of microbial cells by atomic force microscopy.  TOUHAMI, A., NYSTEN, B. and DUFRÊNE, Y.F. Langmuir 19, 2003 

Nanoscale organization of collagen and mixed collagen-Pluronic adsorbed layers.  DE CUPERE, V., VAN WETTER, J. and ROUXHET, P.G. Langmuir 19, 2003 

New approach for the synthesis of amincontaining linear polymers  VAN DE VELDE P., E.J. GOETHALS, F.E. DU PREZ. Polym. Int., 52, 2003 

New class of catalysts for the propane ammoxidation process.  FLOREA M., R. PRADA SILVY, P. GRANGE. Catal. Lett. 87, 2003 

New nanocomposite materials based on plasticized poly(L-lactide) and organo-modified montmorillonites : thermal and morphological study;  PAUL M.-A., ALEXANDRE M., DEGEE Ph., HENRIST C., RULMONT A., DUBOIS Ph. Polymer, 44, 2003 

New thermo-responsive polymer materials based on poly(2-ethyl-2-oxazoline) segments.  CHRISTOVA, R. VELICHKOVA, W. LOOS, E. GOETHALS, F.E. DU PREZ. Polymer, 44, 2003 

Nitrogen incorporation in an Al0.5Ga0.5PO4 amorphous solid with 27Al and 31P NMR  DELSARTE S., P. GRANGE, T. CHEN, P. GROBET, P. JACOBS. J. Phys. Chem. 107, 2003 

Noncovalent functionalization of multi-walled carbon nanotubes by pyrene containing polymers.  PETROV P., F. STASSIN, C. PAGNOULLE, R. JEROME Chem. Commun., 2003 

Novel aliphatic polyesters based on functional cyclic (di)esters.  LOU X., C. DETREMBLEUR, R. JÉRÔME. Macromol. Rapid. Commun., 24, 2003 

Novel chromophore-functionalized poly2-(trifluoromethyl) adamantyl acrylate-methyl vinyl urethanes with high poling stabilities of the nonlinear optical effect.  BRIERS, D; KOECKELBERGHS, G; PICARD, I; VERBIEST, T; PERSOONS, A; SAMYN, C. Macromolecular Rapid Communications 24 (14), 2003 

Nucleation and crystallization in double crystalline poly(p-dioxanone)-b-(?-caprolactone) diblock copolymers  ALBUERNE J., MARQUEZ L., MULLER A.J., RAQUEZ J.M., DEGEE Ph., DUBOIS Ph., CASTELLETV., HAMLEY I.W. Macromolecules, 36, 2003 

Oligothiophene Radical-Cations: Polaron Structure in Hybrid DFT and MP2 Calculations  GESKIN V.M., A. DKHISSI, and J.L. BRÉDAS. International Journal of Quantum Chemistry, 91, 2003 

On the polarization of the green emission of polyfluorenes.  YANG X.H., D. NEHER, C. SPITZ, E. ZOJER, J.L. BRÉDAS, R. GÜNTNER, and U. SCHERF. Journal of Chemical Physics, 119, 2003 

One and two-dimensional semiconducting nanostructures self-assembly of conjugated oligomers.  LECLERE Ph., M. SURIN, P. JONKHEIJM, O. HENZE, A. P. H. J. SCHENNING, F. BISCARINI, A. C. GRIMSDALE, W. J. FEAST, E. W. MEIJER, K. MUELLEN, J.L. BREDAS, R. LAZZARONI. Materials Research Society Symposium Proceedings, 775, 2003 

OperandResonance Raman Spectroscopic Characterization of the Oxidation State of Palladium in Pd/?-Al2O3 Catalysts during the Combustion of Methane.  DEMOULIN O., M. NAVEZ, E. M. GAIGNEAUX, P. RUIZ and A-S. MAMEDE, P. GRANGE and E. PAYEN. Phys. Chem. Chem. Phys., 5, 2003 

Optical and thermal properties of novel diazine-based oligo(phenylenevinylene)s;  MAINIL M., PASCAL L., VANDEN EYNDE J.J., VAN HAVERBEKE Y., DUBOIS Ph. e-Polymer, 056, 2003 

Optical properties and orientation of arrays of polystyrene spheres deposited using convective self-assembly.  WOSTYN, K; ZHAO, YX; YEE, B; CLAYS, K; PERSOONS, A; DE SCHAETZEN, G; HELLEMANS, L. Journal Of Chemical Physics 118 (23), 2003 

Ordered Polyelectrolyte Multilayers. Rules Governing Layering in Organic Binary Multilayers  ARYS, X.; FISCHER, P.; JONAS, A.M.; KOETSE, M.M.; LASCHEWSKY, A.; LEGRAS, R.; WISCHERHOFF, E. J. Am. Chem. Soc. 125, 2003 

Organic semiconductor materials: Fundamental aspects of transport mechanisms.  CALBERT J.P., J. CORNIL, J.L. BREDAS. Chimie Nouvelle, 21, 2003 

Organometallic complexes for nonlinear optics. Part 29. Quadratic and cubic hyperpolarizabilities of stilbenylethynyl-gold and -ruthenium complexes.  HURST, SK; LUCAS, NT; HUMPHREY, MG; ISOSHIMA, T; WOSTYN, K; ASSELBERGHS, I; CLAYS, K; PERSOONS, A; SAMOC, M; LUTHER-DAVIES, B. Inorganica Chimica Acta 350, 2003 

Origin of High Second- and Third-Order Nonlinear Optical Response in Ammonio/BoratDiphenylpolyene Zwitterions: The Role of Polarized Aromatic Groups.  GESKIN V.M., C. LAMBERT, and J.L. BRÉDAS. Journal of the American Chemical Society, 125, 2003 

Oxidation of 2-thiobenzyl-4,6-dimethyl-pyrimidine with hydrogen peroxide over Moxides, Msuboxides and mixed Mo-Sb oxides catalysts.  RADU C., V. CAMPEANU, F. BERTINCHAMPS, E. M. GAIGNEAUX, V. I. PARVULESCU. Catalysis Communication 4, 2003 

Oxidative conversion of isobutane tisobutene over V-Sb-Ni oxide catalysts.  VISLOVSKIY V.P., N.T. SHAMILOV, A.M. SARDARLY, R.M. TALYSHINSKII, V.Yu. BYCHKOV, P. RUIZ, V. CORTES CORBERAN, Z. SCHAY, Zs. KOPPANY. Applied Catal. A:General 250, 2003 

Oxidative dehydrogenation of propane on pure and silica-dispersed multimetallic oxides based on vanadium and niobium prepared via hydrolytic and non-hydrolytic sol-gel methods.  MOGGI P., M. DEVILLERS, P. RUIZ, G. PREDIERI, D. CAUZZI, S. MORSELLI, O. LIGABUE. Catalysis Today 81, 2003 

Packing effects in the liquid phase adsorption of C5-C22 n-alkanes on ZSM-5,  DE MEYER, K., CHEMPATH, S, DENAYER, J.F.M., MARTENS, J.A., SNURR, R.Q., BARON, G.V. J. Phys. Chem. B., 107, 2003 

Pathways for Photoinduced Charge Separation in DNA Hairpins.  BELJONNE, G. POURTOIS, M.A. RATNER, and J.L. BREDAS. Journal of the American Chemical Society, 125,, 2003 

Patterned collagen layers on polystyrene : direct probing using AFM in the adhesion mapping mode.  DUPONT-GILLAIN, Ch. C., JACQUEMART, I. Surface Science 539, 2003 

Performance and acceptability of intrauterine release of levonorgestrel with a mini delivery system for hormonal substitution therapy, contraception and treatment in perimenopausal and postmenopausal women.  WILDEMEERSCH D., E. SCHACHT, P. WILDEMEERSCH. Maturitas 44, 2003 

Performance Limits of Isothermal Packed Bed and Perforated Monolithic Bed Reactors Operated Under Laminar Flow Conditions. I. General Optimization Analysis,  DESMET, G., DEGREEF, J., VERELST, H. and BARON, G. V., Chemical Engineering Science 58, 2003 

Performance Limits of Isothermal Packed Bed and Perforated Monolithic Bed Reactors Operated Under Laminar Flow Conditions. II. Performance Comparison and Design Considerations.  DESMET, G., DEGREEF, J., VERELST, H. and BARON, G. V. Chemical Engineering Science 58, 2003 

Ph. New aliphatic polyester layered silicate nanocomposites; Biodegradable Polymers and Plastics, Chiellini E. and SolarR  POLLET E., PAUL M.-A., DUBOIS Ph. Eds., Kluwer Academic Plenum Publishers, New York (USA), Chap. 22, 2003 

Pharmacology of inositol triphosphate receptors.  BULTYNCK G., I. SIENAERT, J. B. PARYS, G. CALLEWAERT, H. DE SMEDT, N. BOENS, W. DEHAEN, L. MISSIAEN. Pflug. Arch.-Eur. J. Physiol. 445, 2003 

Photoadduct leading tcrosslinking in Ru(II) derivatized oligonucleotides.  LENTZEN O., J.-F. CONSTANT, E. DEFRANCQ, C. MOUCHERON, P. DUMY, A. KIRSCH – DE MESMAEKER. Nucleosides, Nucleotides & Nucl. Acids, 22 (N° 5-8), 2003 

Photo-crosslinking in Ru-labelled duplex oligonucleotides.  LENTZEN O., J.F. CONSTANT, E. DEFRANCQ, M. PRÉVOST, S. SCHUMM, C. MOUVHERON, P. DUMY, A. KIRSCH – DE MESMAEKER. ChemBioChem. 4, 2003 

Photoluminescence intensity fluctuations and electric field induced photoluminescence quanching in individual nanoclusters of poly(phenylenevinylene)  SCHEBLYKIN G., ZORINIANTS J., HOFKENS S., DE FEYTER M., VAN DER AUWERAER F., C. DE SCHRYVER. ChemPhysChem., 4, 260-267 (2003), 2003 

Photophysical properties of Ru(II) polyazaaromatic compounds : a theoretical insight.  POURTOIS, D. BELJONNE, C. MOUCHERON, S. SCHUMM, A. KIRSCH – DE MESMAEKER, R. LAZZARONI, J.L. BREDAS. J. Am. Chem. Soc., 2003 

Physicochemical and biological evaluation of cationic polymethacrylates as vectors for gene delivery.  DUBRUEL P., B. CHRISTIAENS, B. VANLOO, K. BRACKE, M. ROSSENEU, J. VANDEKERKHOVE & E. SCHACHT European Journal of Pharmaceutical Sciences 18(3-4), 2003 

Plant lectin-like bacteriocin from a rhizosphere-colonizing Pseudomonas isolate  PARRET AHA, SCHOOFS G, PROOST P and DE MOT R. J. Bacteriol. 185, 2003 

Polarized infrared study of hybrid Langmuir-Blodgett monolayers containing clay mineral nanoparticles.  RAS R.H.A., C.T. JOH. Langmuir 19, 2003 

Polaron Pair vs. Bipolaron on Oligothiophene Chains: A Theoretical Study of the Singlet and Triplet States.  GESKIN V.M. and J.L. BRÉDAS. ChemPhysChem, 4, 2003 

Polyelectrolyte multilayers as nanocontainers for functional hydrophilic molecules,  NICOL, E., HABIB-JIWAN, J.-L., JONAS, A.M Langmuir 19, 2003 

Poly-L-glutamic acid derivatives as multifunctional vectors for gene delivery. Part A. Synthesis and physicochemical evaluation.  DUBRUEL P., L. DEKIE & E. SCHACHT. Biomacromolecules 4, 2003 

Poly-L-glutamic acid derivatives as multifunctional vectors for gene delivery. Part B. Biological evaluation  DUBRUEL P., L. DEKIE, B. CHRISTIAENS, B. VANLOO, M. ROSSENEU, J. VAN DE KERCKHOVE, M. MANNISTO, A. URTTI & E. SCHACHT. Biomacromolecules 4, 2003 

Polymer Chemistry for the Design of New Materials (introduction as guest editor of special issue).  DU PREZ. Polym. Int., 52, 2003 

Polymer Coating of Steel by a Combination of Electrografting and Atom-Transfer Radical Polymerization.  CLAES M., S. VOCCIA, C. DETREMBLEUR, C. JEROME, B. GILBERT, Ph. LECLERE, V.M. GESKIN, R. GOUTTEBARON, M. HECQ, R. LAZZARONI, R. JEROME. Macromolecules, 36, 2003 

Polymer layered silicate nanocomposites by combined intercalative polymerization and melt intercalation: masterbatch process.  LEPOITTEVIN B., DEVALKENAERE M., ALEXANDRE M., PANTOUSTIER N., CALBERG C., JEROME R., HENRIST C., RULMONT A., DUBOIS Ph. Polymer 44, 2003 

Polymer materials for second-order non-linear optical applications.  SAMYN, CA; VAN DEN BROECK, K; GUBBELMANS, E; BALLET, W; VERBIEST, T; PERSOONS, A. Optical Materials 21 (1-3), 2003 

Polymerization of ?-caprolactone initiated by yttrium alkoxide grafted ontporous silica;  MARTIN E., DUBOIS Ph., JÉRÔME R. Macromolecules, 36, 2003 

Polymerization-filled composites and nanocomposites by coordination catalysis  DUBOIS Ph., ALEXANDRE M., JÉRÔME R. Macromol. Symp., 194, 2003 

Pore mouth physisorption of alkanes on ZSM-22: Estimation of physisorption enthalpies and entropies by additivity.  LAXMI NARASIMHAN C.S., J. W. THYBAUT, G. B. MARIN, J. A. MARTENS, J. F. DENAYER, and G. V. BARON. J. Catal., 218, 2003 

Pore mouth versus intracrystalline adsorption of isoalkanes on ZSM-22 and ZSM-23 zeolites under vapour and liquid phase conditions.  DENAYER J.F., A. R. OCAKOGLU, W. HUYBRECHTS, J. A. MARTENS, J. W. THYBAUT, G. B. MARIN and G. V. BARON. Chem. Comm. 15, 2003 

Poremouth and Key-lock Physisorption modes of alkanes on ZSM-22  NARASIMHAN, C.S.L., THYBAUT, J.W., DENAYER, J.F.M., BARON, G.V., MARTENS, J.A., MARIN, G.B., J. Catal., 218., 2003 

Porphotetramethenes (Calix4]pyrroletetraquinomethides) From Oxidative N-Alkylation of Porphyrin Tetraphenols  DOLUSIC E., S. SMEETS, S. TOPPET, B. TINANT, L. VAN MEERVELT, W. DEHAEN. Tetrahedron, 59, 2003 

Practical Heterogeneous Catalysts for Epoxide Production.  DE VOS D.E., SELS B., and JACOBS P.A. Adv. Synth. Cat., 345,, 2003 

Preferential Siting of Iron Atoms in MFI Type Ferrisilicate Zeolite Framework: An Attempt tExplain Experimental Data with TPA-Silicate Solution Chemistry  THEUNISSEN E., KIRSCHHOCK C., KREMER S.P.B., HABERMACHER D., and MARTENS J.A. Eur. J. Inorg. Chem., 2003 

Preparation of macroporous biodegradable poly(L-lactide-co-e-caprolactone) foams and characterization by mercury intrusion porosimetry, image analysis, and impedance spectroscopy.  MAQUET V., S. BLACHER, R. PIRARD, J.P. PIRARD, M. VYAKARNAM, R. JÉRÔME. J. of Biomedical Materials Research, Part A, 66(2), 2003 

Preparation of reactive surfaces by electrografting.  JEROME, S. GABRIEL, S. VOCCIA, C. DETREMBLEUR, M. IGNATOVA, R.GOUTTEBARON, R. JEROME. ChemComm,, 2003 

Preparation of supported yttrium alkoxides as catalysts for the polymerization of lactones and oxirane.  MARTIN E., Ph. DUBOIS, R. JÉRÔME. J. Polym. Sci., Part A: Polym.Chem., 41, 2003 

Preparation, characterization and in vitrdegradation of bioresorbable and bioactive composites based on bioglass-filled polylactide foams.  MAQUET V., L. PRAVATA, I. NOTHINGER, R. JÉRÔME. J. of Biomedical Materials Research, Part A, 66(2), 2003 

Probing Förster type energy pathways in a first generation rigid dendrimer bearing twperylene imide chromophores.  VOSCH T., M. COTLET, J.HOFKENS, K. VAN DER BIEST, M. LOR, K. WESTON, Ph.TINNEFELD, M. SAUER, L. LATTERINI, K. MÜLLEN, F.C. DE SCRYVER. J.Phys.Chem., 107, 36, 2003 

Probing of the reaction progress at a PMMA/PS interface by using anthracene-labeled reactive PS chains.  YIN Z., C. KOULIC, C. PAGNOULLE, R. JEROME. Langmuir, 19, 2003 

Probing specific lectin-carbohydrate interactions using atomic force microscopy imaging and force measurements  TOUHAMI, A., HOFFMANN, B., VASELLA, A., DENIS, F.A. and DUFRÊNE, Y.F. Langmuir 19, 2003 

Propane ammoxidation catalyst based on vanadium-aluminum oxynitride.  PRADA SILVY R., M. FLOREA, N. BLANGENOIS And P. GRANGE. AIChE Journal 49, 2003 

Quadratic optical nonlinearities of N-methyl and N-aryl pyridinium salts.  COE, BJ; HARRIS, JA; ASSELBERGHS, I; WOSTYN, K; CLAYS, K; PERSOONS, A; BRUNSCHWIG, BS; COLES, SJ; GELBRICH, T; LIGHT, ME; HURSTHOUSE, MB; NAKATANI, K. Advanced Functional Materials 13 (5), 2003 

Quantitative relations between liquid phase adsorption and catalysis,  DE VOS D.E., G.V. BARON, F. VAN LAAR, P.A. JACOBS, Nanostructured Catalysts, Ed. S. Scott et al, Kluwer Academic Publishers,, 2003 

Quantum Chemistry as a Tool for the Study of Electronic and Optical Processes in Organic Materials.  LEMAUR V., E. HENNEBICQ, J. CORNIL, D. BELJONNE, and J.L. BRÉDAS. Chimie Nouvelle 82, 2003 

Radiolabeling of Pluronic amphiphilic copolymer for adsorption studies  DE CUPERE, V.M., BILTRESSE, S., MARCHAND-BRYNAERT, J. and ROUXHET, P.G. J. Colloid Interf. Sci. 259, 2003 

Reactively and physically compatibilized immiscible polymer blends : stability of the copolymer at the interface.  HARRATS, K. DEDECKER, G. GROENINCKX, R. JÉRÔME. Macromol. Symp., 198, 2003 

Real-time imaging of the surface topography of living yeast cells by atomic force microscopy.  AHIMOU, F., TOUHAMI, A. and DUFRÊNE, Y.F Yeast 20, 2003 

Recent progress in the application of atomic force microscopy imaging and force spectroscopy tmicrobiology.  DUFRÊNE, Y.D. Current Opinion in Microbiology 6, 2003 

Recycling of Homogeneous Hydrogenation Catalysts by Dialysis Coupled Catalysis.  DE SMET K., PLEYSIER A., VANKELECOM I.F.J., and JACOBS P.A. Chem. Eur. J., 9, 2003 

Refining catalyst market update  PRADA SILVY R Oil & Gas European Magazine 2, 2003 

Regioselective end-functionalization of polylactide oligomers with d-glucose and d-galactose;  BERNARD K., DEGEE Ph., DUBOIS Ph Polym. International, 52, 2003 

Revealing Competitive Förster-type Resonance Energy-Transfer Pathways in Single Bichromophoric Molecules.  HOFKENS Johan, Mircea COTLET, Tom VOSCH, Philip TINNEFELD, Kenneth D. WESTON, Christophe EGO, Andrew GRIMSDALE, Klaus MÜLLEN, David BELJONNE, Jean-Luc BRÉDAS, Sven JORDENS, Gerd SCHWEITZER, Markus SAUER, and Frans DE SCHRYVER. Proc. Nat. Acad. Sci. 100,, 2003 

Revealing competitive Förster-type resonant energy transfer pathways in single bichromophoric molecules  HOFKENS J., M. COTLET, T. VOSCH, P. TINNEFELD, K.D. WESTON, C. EGO, A. GRIMSDALE, K. MÜLLEN, D. BELJONNE, J.-L. BRÉDAS, S. JORDENS, G. SCHWEITZER, M. SAUER, F.C. DE SCHRYVER. Proc.Acad.Sci. USA100, 2003 

Reversible chemical patterning on stimuli-responsive polymer film: Environment-responsive lithography.  IONOV L., S. MINKO, M. STAMM, J.F. GOHY, R. JÉRÔME, A. SCHOLL. Journal of the American Chemical Society, 125, 2003 

Reversible intramolecular Electron Transfer at the Single Molecule Level  GRONHEID R., A. STEFAN, M. COTLET, J.HOFKENS, J.QU, K. MÜLLEN, M. VAN DER AUWERAER, J.W. VERHOEVEN, F.C. DE SCHRYVER. Angew.Chem., 42, 4209-4214 (2003), 2003 

Ru(TAP)2(DPPZ)]2+ : a DNA binding complex, which luminesces strongly in water and undergoes photo-induced proton-coupled electron transfer with GMP.  ORTMANS I., B. ELIAS, J.M. KELLY, C. MOUCHERON, and A. KIRSCH – DE MESMAEKER. Dalton Trans. (RCS), 2003 

Ruthenium (II) dendrimers containing carbazole-based chromophores as branches”,  MCCLENAGHAN N.D., R. PASSALACQUA, F. LOISEAU, S. CAMPAGNA, B. VERHEYDE, A. HAMEURLAINE, W. DEHAEN. J. Am. Chem. Soc. 125, 2003 

Second-order nonlinear optical properties of chiral materials.  SIONCKE, S; VERBIEST, T; PERSOONS, A. Materials Science & Engineering R-Reports 42 (5-6), 2003 

Segmented polymer networks containing amino-dendrimers.  TANGHE L., E. GOETHALS, F. DU PREZ. Polym. Int., 52, 2003 

Selective catalytic reduction of Nby NH3 on sulfate titania pillared clay.  KHALFALLAH BOUDALI L., A. GHORBEL, P. GRANGE. Catal. Lett. 86, 2003 

Selective catalytic reduction of Nwith NH3 over mesoporous V2O5-TiO2-SiO2 catalysts.  PARVULESCU V.I., S. BOGHOSIAN, V. PARVULESCU, S.M. JUNG, P. GRANGE. J. Catal. 217, 2003 

Self-organization of water-soluble complexes of a poly(2-vinylpyridinium)-block-poly(ethylene oxide) diblock with fluorinated anionic surfactants.  GOHY J.F., S. MORES, S.K. VARSHNEY, R. JÉRÔME. Macromolecules, 36, 2579-2581 (2003), 2003 

Silylation reaction of dextran: effect of experimental conditions on silylation yield, regioselectivity and chemical stability of silylated dextrans  NOUVEL C., DUBOIS Ph., DELLACHERIE E., SIX J.-L. Biomacromolecules, 4, 2003 

Single-electron Transistor of a single organic molecule with access tseveral redox states.  KUBATKIN S., A. DANILOV, M. HJORT, J. CORNIL, J.L. BRÉDAS, N. STUHR-HANSEN, P. HEDEGARD, and T. BJØRNHOLM. Nature, 425, 2003 

Single-molecule surface enhanced resonance Raman spectroscopy of the enhanced green fluorescent protein (EGFP).  HABUCHI S, COTLET M, GRONHEID R, DIRIX G, MICHIELS J, VANDERLEYDEN J, DE SCHRYVER F and HOFKENS J. Journal of the American Chemical Society, 125(28), 2003 

Solid-state NMR relaxometry study of phenolic resins.  ADRIAENSENS P., R. REGO, R. CARLEER, B. OTTENBOURGS and J. GELAN. Polymer International, 52, 2003 

Solvent-free synthesis and purification of poly(2-(dimethylamino)ethyl methacrylate by atom transfer radical polymerisation.  PANTOUSTIER N., MOINS S., WAUTIER S., DEGEE Ph., DUBOIS Ph. Chemical Communications, 3, 2003 

Spatially heterogeneous dynamics in polymer glasses at room temperature probed by single molecule lifetime fluctuations.  VALLÉE R.A.L., M. COTLET, J. HOFKENS, F.C. DE SCHRYVER, K. MÜLLEN. Macromolecules, 36, nr 20, 2003 

SSO, H. MARCUS, S. MARDER, J. PERRY, C. RISKO, F. STELLACCI, W. WENSELEERS, E. ZOJER. Two-photon absorption and mixed-valence properties of dioxaborine derivatives  BARLOW S., J.L. BREDAS, V. COROPCEANU, C. GRASSO, H. MARCUS, S. MARDER, J. PERRY, C. RISKO, F. STELLACCI, W. WENSELEERS, E. ZOJER. 225th ACS National Meeting, Abstracts of Papers,, 2003/Mar 

Sterically Encumbered Porphyrins by Suzuki Reactions of a 5,15-Bis(4,6-dichloropyrimidin-5-yl) Derivative.  MAES W., W. DEHAEN. Synlett, 2003 

Structure and mesomorphic behaviour of alkoxy-substituted bis(phthalocyaninato)-lanthanide(III) complexes.  BINNEMANS K., J. SLEVEN, S. DE FEYTER, F.C. DE SCHRYVER, B. DONNIand D. GUILLON. Chemistry of Materials, 15, 2003 

Supramolecular Control of two-dimensional phase behavior.  DE FEYTER S., M. LARSSON, N. SCHUURMANS, B. VERKUIJL, G. ZORINIANTS, A. GESQUIÈRE, M.M. ABDEL-MOTTALEB, J. VAN ESCH, B.L. FERINGA, J. VAN STAM, F.C. DE SCHRYVER. Chem.Eur.J. 9, N°5,, 2003 

Supramolecular Organization in Block Copolymers Containing a Conjugated Segment: A Joint AFM/Molecular Modeling Study.  LECLÈRE Ph., E. HENNEBICQ, A. CALDERONE, P. BROCORENS, A.C. GRIMSDALE, K. MÜLLEN, J.L. BRÉDAS, and R. LAZZARONI. Progress in Polymer Science, 28, 2003 

Surface Characterization of Poly(?-caprolactone)-based Nanocomposites.  VIVILLE P., R. LAZZARONI, E. POLLET, M. ALEXANDRE, P. DUBOIS ; G. BORCIA, J.J. PIREAUX. Langmuir, 19, 2003 

Surface initiated polymerization from poly(ethylene terephthalate)  ROUX, S., DEMOUSTIER-CHAMPAGNE, S. Journal of Polymer Science : Part A : Polymer Chemistry 41, 2003 

Synthesis and characterisation of water-soluble poly(ethylene glycol) modified polymethacrylates with the ability tcrosslink.  SNELLINGS G., W. MONDELAERS & E. SCHACHT. Polym. Int. 52, 2003 

Synthesis and characterization of random copolyesters of ?-caprolactone and 2-Oxepane-1,5;  LATERE J-P., LECOMTE Ph., DUBOIS Ph., JÉRÔME R. Macromolecules, 36, 2003 

Synthesis and characterization of random copolyesters of ?-caprolactone and 2-oxepane-1,5-dione.  LATERE J.P., Ph. LECOMTE, Ph. DUBOIS, R. JÉRÔME. Macromolecules, 36, 2003 

Synthesis and Characterization of Water-Soluble Amphipatic Polystyrene-Based Dendrigrafts  SCHAPPACHER M., A. DEFFIEUX, J.L. PUTAUX, P. VIVILLE, and R. LAZZARONI. Macromolecules, 36, 2003 

Synthesis and optical properties of polyphenylene dendrimers based on perylenes.  QU J., D. LIU, S. DE FEYTER, J. ZHANG, F.C. DE SCHRYVER, K. MÜLLEN. J. Org.Chem., 68, 25,, 2003 

Synthesis and Photomodulation of Rigid Polyphenylene Dendrimers with an azobenzene core.  GREBEL-KOEHLER D., D. LIU, S. DE FEYTER, V. ENKELMANN, T. WEIL, C. ENGELS, C. SAMYN, K.  MÜLLEN, F.C. DE SCHRYVER. Macromolecules, 36, 3, 2003 

Synthesis and properties of chiral chromophore-functionalised polybinaphtalenes for nonlinear optics: Influence of chromophore concentration.  KOECKELBERGHS, G; SIONCKE, S; VERBIEST, T; VAN SEVEREN, I; PICARD, I; PERSOONS, A; SAMYN, C. Macromolecules 36, 2003 

Synthesis and properties of chiral donor-embedded polybinaphthalenes for nonlinear optical applications  KOECKELBERGHS, G; SIONCKE, S; VERBIEST, T; PERSOONS, A; SAMYN, C. Chemistry Of Materials 15 (15), 2003 

Synthesis and properties of chiral helical chromophore-functionalised polybinaphthalenes for second-order nonlinear optical applications.  KOECKELBERGHS, G; SIONCKE, S; VERBIEST, T; PERSOONS, A; SAMYN, C. Polymer 44 (14), 2003 

Synthesis of an oxyamincontaining phenanthroline derivative for the efficient preparation of phenanthroline oligonucleotide oxime conjugates.  DEROS., E. DEFRANCQ, C. MOUCHERON, A. KIRSCH – DE MESMAEKER, P. DUMY. Tet.Letters, 44 /46,, 2003 

Synthesis of chiral helical chromophore-functionalized polybinaphthalenes.  KOECKELBERGHS, G; DE GROOF, L; SIONCKE, S; VERBIEST, T; PERSOONS, A; SAMYN, C. Macromolecular Rapid Communications 24 (5-6), 2003 

Synthesis of Co-rich CoAPO-5 Molecular Sieves: A Comparison between Glycerol and Water as Solvent.  FAN W. and WECKHUYSEN B.M J. Nanosc. Nanotech, 3,, 2003 

Synthesis of novel dendrimers containing pyrimidine units  MAES W., D. AMABILINO, W. DEHAEN. Tetrahedron, 59, 2003 

Synthesis of novel dendritic molecules based on pyrroloanthracene units.  SMET M., D. CORENS, W. DEHAEN. ARKIVOC, IV, 2003 

Synthesis of poly(tetrahydrofuran)-b-poly(styrene) block copolymers from duo-initiators for CROP and ATRP  BERNAERTS K., E. SCHACHT, E. GOETHALS, F. DU PREZ. J. Polym. Sci., Part A: Polym. Chem., 41, 2003 

Synthesis of soluble oligocarbazole derivatives.  HAMEURLAINE, W. DEHAEN. Tetrahedron Lett. 44, 2003 

Synthesis, degradation, and antimicrobial properties of targeted macromolecular prodrugs of norfloxacin.  ROSEEUW E., V. COESSENS, A-M. BALAZUC, M. LAGRANDERIE, P. CHAVAROT, A. PESSINA, M.G. NERI, E. SCHACHT, G. MARCHAL & D. DOMURADO. Antimicrobial Agents and Chemotherapy 47(11), 2003 

Synthesis, separation, and isomer-dependent packing in twdimensions - detected by scanning tunnelling microscopy - of a TTF derivative.  GOMAR-NADAL, M.M.S. ABDEL-MOTTALEB, S. DE FEYTER, J. VECIANA, C. ROVIRA, D.B. AMABILINO, F.C. DE SCHRYVER. Chem.Comm., 2003 

Temporal Analysis of Products: basic principles, applications and theory.  YABLONSKY G.S., M. OLEA and G.B. MARIN. J. Catal. 216, 2003 

Tensioactive properties of poly(R,S)-? -malic acid-b-?-caprolactone] diblock copolymers in aqueous solution  COULEMBIER O., DEGEE Ph., GUERIN Ph., DUBOIS Ph. Langmuir, 19, 8661-8666 (2003), 2003 

The Active Role of CO2 at Low Temperature in Oxidation Processes: the case of the Oxidative Dehydrogenation of Propane on NiMoO4 Catalysts.  DURY, E.M. GAIGNEAUX and P. RUIZ Appl. Catal. A: General 242, 2003 

The diastereoisomeric forms of a mononuclear Ru(II) complex bearing a bis-phenanthroline Tröger’s base analogue.  BRESSON, M. LUHMER, M. DEMEUNYNCK, A. KIRSCH – DE MESMAEKER, F. PIERARD. Tet. Letters, 2003 

The effects of abrupt T-outlets in a riser : 3D simulation using the kinetic theory of granular flow,  DE WILDE J., Guy B. MARIN, Geraldine J. HEYNDERICKX. Chem. Eng. Sci. 58, 2003 

The influence of an acid-base-equilibrium on the adsorption behavior of a weak polyampholyte.  MAHLTIG, R. JÉRÔME, M. STAMM. J. Polym. Research, 10, 2003 

The macrolide antibiotic azithromycin interacts with lipids and affects membrane organization and fluidity : studies on Langmuir-Blodgett monolayers, liposomes and J774 macrophages.  TYTECA, D., SCHANCK, A., DUFRÊNE, Y.F., DELEU, M., COURTOY, P.J., TULKENS, P.M. and MINGEOT-LECLERCQ, M.P. J. Membrane Biol. 192, 2003 

The oil refining industry and catalyst market in Western Europe.  PRADA SILVY R. Oil & Gas European Magazine 4, 2003 

The Role of the Solvent in the Asymmetric Hydrogenation of ?-ketesters with Ru-BINAP  WOLFSON A., VANKELECOM I.F.J., GERESH S., and JACOBS P.A. J. Molec. Cat, 198, 39-45, 2003, 2003 

The Role of Vibronic Interactions on Intra- and Inter-Molecular Electron Transfer in ?-Conjugated Oligomers.  COROPCEANU V., J.M. ANDRÉ, M. MALAGOLI, and J.L. BRÉDAS. Theoretical Chemistry Accounts, 110, 2003 

The thiocarbamate-inducible Rhodococcus enzyme ThcF as a member of the family of ?/? hydrolases with haloperoxidative side-activity.  DE MOT R, DE SCHRIJVER A, SCHOOFS G and PARRET AHA. FEMS Microbiol. Lett. 224, 2003 

Theoretical Investigation of the Origin of Negative Differential Resistance in Substituted Phenylene Ethynylene Oligomers.  KARZAZI Y., J. CORNIL, and J.L. BRÉDAS. Nanotechnology, 14, 2003 

Theoretical Investigation of the Spin-dependent Exciton Formation Rates in Polymeric Light-emitting Diodes  SHUAI Z., S. YIN, A. YE, D. BELJONNE, and J.L. BRÉDAS. Journal of the Chinese Chemical Society, 50, 2003 

Thermo-responsive and emulsifying properties of poly(N-vinyl caprolactam) based graft copolymers.  VERBRUGGHE S., K. BERNAERTS, F.E. DU PREZ. Macromol. Chem. Phys., 204, 2003 

Thermo-responsive organic/inorganic hybrid hydrogels based on poly(N-vinyl caprolactam).  LOOS W., S. VERBRUGGHE, E. GOETHALS, F.E. DU PREZ, I. BAKEEVA, V. ZUBOV. Macromol. Chem. Phys., 204, 2003 

Three genes encoding for putative methyl- and acetyltransferases map adjacent tthe wzm and wzt genes and are essential for O-antigen biosynthesis in Rhizobium etli CE3.  LEROUGE I, VERRETH C, MICHIELS J, CARLSON RW, DATTA A, GAMY, VANDERLEYDEN J. MPMI 16, 2003 

Three-Dimensional Band Structure and Bandlike Mobility in Oligoacene Single Crystals: A Theoretical Investigation.  CHEN Y.C., R.J. SILBEY, D.A. DA SILVA-FILHO, J.P. CALBERT, J. CORNIL, and J.L. BRÉDAS. Journal of Chemical Physics, 118, 2003 

Three-Dimensional Simulation of a Fluid Catalytic Cracking Riser Reactor,  ASIT K. DAS, Edward BAUDREZ, Guy B. MARIN, and Geraldine J. HEYNDERICKX. Ind. Eng. Chem. Res. 42, 2003 

Toward a Better Control of Internal Structure and External Morphology of Mesoporous Silicas Synthesized Using a Nonionic Surfactant.  LÉONARD A., BLIN J.L., ROBERT M., JACOBS P.A., CHEETHAM A.K., and SU B.-L. Langmuir, 19, 2003 

Toward Waste-Free Production of Heck Products with a Catalytic Palladium System under Oxygen.  DAMS M., DE VOS D.E., CELEN S., and JACOBS P.A. Angew. Chem. (Int. Edit. ), 42, 2003 

Towards two-dimensional supramolecular control of hydrogen-bonded arrays : the case of isophthalic acids  DE FEYTER S., A. GESQUIÈRE, M. KLAPPER, K. MÜLLEN, F.C. DE SCHRYVER. NanLetters, 3, 11,, 2003 

Tracer chromatographic Adsorption Studies in Relation tLiquid Phase Catalysis,  DE VOS, D.E., DENAYER, J., VAN LAAR, F., BARON, G.V., JACOBS, P.A., Topics in Catalysis, 23 (1-4),, 2003 

Tracer chromatographic study of pore and pore mouth adsorption of linear and monobranched alkanes on ZSM-22 zeolite,  OCAKOGLU R.A., J.F.M. DENAYER, G.B. MARIN, J.A.MARTENS and G. V. BARON J.Phys. Chem. B 107, 2003 

Tracer. Chromatographic Study of Pore and Pore Mouth Adsorption of Linear and Monobranched Alkanes on ZSM-22 Zeolite.  OCAKOGLU, A.R., DENAYER, J.F.M., MARIN, G.B., MARTENS, J.A., BARON, G.V. J. Phys. Chem. B, 207,, 2003 

Transition Metal anion exchanged Layered Double Hydroxides as a bioinspired model of Vanadium Bromoperoxidase.  SELS B., DE VOS D.E., BUNTINX M., and JACOBS P.A. J. Catal., 216, 2003 

Transport and size fractionation of nanoparticles in stepwise tapered nanometric thin channels, Proceedings of µTAS 2003 Seventh International Conference on MicrTotal Analysis Systems,  CLICQ, S. VANKRUNKELSVEN, G. V. BARON and G. DESMET ISBN: 0-9743611-0-0, 2003 

Twisted ?-System Electro-Optic Chromophores - CIS vs. MRD-CI Theoretical Investigation.  KEINAN S., E. ZOJER, J.L. BRÉDAS, M.A. RATNER, and T.J. MARKS. Theochem, 633, 2003 

Two-dimensional supramolecular self-assembly probed by scanning tunneling microscopy.  DE FEYTER S., F.C. DE SCHRYVER. Chem.Soc.Review, 32,, 2003 

Use of functionalized atomic force microscopy probes in biophysics.  DUFRÊNE, Y.F. Microscopy and Analysis 97, 2003 

Use of X-ray photoelectron spectroscopy and atomic force microscopy for studying interfaces in biofilms  ROUXHET, P.G., DUPONT-GILLAIN, C.C., GENET, M.J. and DUFRÊNE, Y.F. Biofilms in Medecine, Industry and Environmental Biotechnolog - IWA Publishing, London, Ch. 16,, 2003 

Vapor barrier properties of polycaprolactone montmorillonite nanocomposites : effect of clay dispersion.  GORRASI G., TORTORA M., VITTORIA V., POLLET E., LEPOITTEVIN B., ALEXANDRE M., DUBOIS Ph. Polymer, 44, 2003 

XPS characterization of zirconium-promoted CoMhydrodesulfurization catalysts  DAMYANOVA S., L. PETROV, P. GRANGE. Appl. Catal. A:General 239, 2003 


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